- Brother-in-law of Katherine Heigl.
- Met Hillary Scott through her MySpace page.
- Met Dave Haywood in middle school.
- Charles and Dave co-wrote friend and labelmate Luke Bryan's hit "Do I".
- Younger brother of singer Josh Kelley.
- A longtime fan of The Beatles, Kelley had an excerpt from Paul McCartney's song "Blackbird" tattooed on his right arm - "All your life you were only waiting for this moment to arise" - aptly heralding the occasion of the band's European breakthrough, a market the trio had dearly wanted to crack (interview: BBC's Episode dated 10 August 2010 (2010)).
- Married Cassie McConnell in a civil ceremony in Nashville in June 2009 then had a destination wedding over the Fourth of July, 2009 weekend in the Bahamas.
- Became engaged to longtime girlfriend Cassie McConnell on Christmas Day 2008.
- Met his girlfriend Cassie McConnell through his brother Josh Kelley, McConnell is Josh's publicist.
- Began dating his now wife, publicist Cassie McConnell in 2006.
- Used to work construction with his brother John.
- Became a father for the 1st time at age 34 when his wife Cassie (née McConnell) Kelley gave birth to their son Ward Charles Kelley on February 11, 2016.
- Member of country music band Lady A comprising fellow musicians Hillary Scott (vocals) and Dave Haywood (vocals/keyboards/mandolin).
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